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Formal Total Synthesis of Salicylihalamides A and B.

✍ Scribed by Georgina A. Holloway; Helmut M. Huegel; Mark A. Rizzacasa


Publisher
John Wiley and Sons
Year
2003
Weight
57 KB
Volume
34
Category
Article
ISSN
0931-7597

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Total Synthesis of Salicylihalamides A a
✍ Christian Herb; Alexander Bayer; Martin E. Maier πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 365 KB πŸ‘ 2 views

## Abstract The paper illustrates two efficient routes to macrolactone **19** containing a 3‐(__para__‐methoxybenzyloxy)propyl side chain at C‐15. The chiral center at C‐15 was introduced by a Noyori reduction of keto ester **5**. The intermediate common to both routes, aldehyde **8**, was prepared

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