This study was initiated to investigate the potential of on-line liquid-liquid extraction with membrane barriers coupled to liquid chromatographic systems for the fully automated purification and enrichment of complex samples containing very low analyte concentrations. As an illustration, a routine
Flow-injection analysis determination of phenols in kerosene and naphtha by membrane extraction-preconcentration
✍ Scribed by Encarnación Rodríguez Gonzalo; José Luis Pérez Pavón; Jaromir Ruzicka; Gary D. Christian; Don C. Olson
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 703 KB
- Volume
- 259
- Category
- Article
- ISSN
- 0003-2670
No coin nor oath required. For personal study only.
✦ Synopsis
The determmatlon of phenohc compounds m kerosene by flow-mjectlon analysis has been mvestlgated The approach IS based on the reactlon of phenols urlth 4-ammoanttpyrme m the presence of an oxldlzmg agent to form red compounds easdy detectable at 500 nm Phenohcs are separated from kerosene through a slhcone membrane mto a basx acceptor stream which mntams the 4-ammoantlpyrme reagent followed by confluence with the oxldlzmg reagent The sensitivity of the system can be easdy manipulated by modlfymg the size of the extraction cell and the preconcentratlon time Direct UV detection at 240 nm was also tested, the acceptor stream bemg a basic buffered solution
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