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Flash photolysis resonance fluorescence investigation of the reactions of OH radicals with OCS and CS2

✍ Scribed by Michael J. Kurylo

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 443 KB
Volume: 58
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)80285-1

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✦ Synopsis

Rate constants for the reaction of OH radicals with CCS and CS, have been determined at 296 K using the flash photolysis resonance fh~orescen~ technique. The values derived from this study are kOH +mS = (5.66 * 1.21) X lo-l4 cm3 mokcuk-' s-l a& _+OH + CS2 = (1 .I35 2 0.34) X lOmu cm3 molecu!e-' s-l, where the uncertaintks are 95% confidence limits making allowance for possible systematic errors.

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