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OCS formation in the reaction of OH with CS2

✍ Scribed by B.M.R. Jones; J.P. Burrows; R.A. Cox; S.A. Penkett

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 370 KB
Volume: 88
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83028-5

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✦ Synopsis

A steady-state system involvmg phato~s~ of HONO asa source of OH was used to ~~e5trgate the reaction of OH wtth CS2 at 1 atm and 295 Ii. In the presence of 02 (240 Torr) a rapid reaction of OH with CSz occurs giving OCS. At lower Oz concentrafionq 0C.S formation ceases. fn au the overall rate constant for OH + CS2 + OCS was (I.7 i 0.9) x W2 cm3 molecule-' s-' *

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