A reinvestigation of the Cl + ClONO2 reaction by flash photolysis resonance fluorescence
โ Scribed by Michael J. Kurylo; Geoffrey L. Knable; Jennifer L. Murphy
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 400 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The reaction of Cl atoms with chlorine nitrate has been reinvestigated by flash photolysis resonance fluorcsccnce over the temperature range 220-296 I;. The new results can be tit to the Arrhenius expression kr = 7.3 X 10-r* esp(165/7I cm3 molecule-' s-l, in good agreement with another recent study but significantly different from our earlier work. Reasons for these differences are suggested and their sigrificance discussed.
๐ SIMILAR VOLUMES
The flash photolysis resonance fluorescencc technique has been used to measure the rrtte constant for the rcaction of O(3P) atoms with CION at 10 torr total pressure over the temperature range 225-273 K. The values obtained can be fit to the Arrhenius equation kr = (1.87 f 1.29) X 10-12 exp[ -(692 i
## Abstract The flash photolysis resonance fluorescence technique has been used to measure the rate constant for the reaction equation image over the temperature range of 250โ370 K. The present results are in excellent agreement with three very recent studies, and the combined data set can been u
Rate constants for the reaction of OH radicals in a homogeneous gas phase reaction with dhnethyl sulfide have been determined using the flash photolysis resonance fluorescence technique over the temperature range 273400 K. The data (combined with the results of another recent study) can be fit to th
Rate constants for the reaction of OH radicals with CCS and CS, have been determined at 296 K using the flash photolysis resonance fh~orescen~ technique. The values derived from this study are kOH +mS = (5.66 \* 1.21) X lo-l4 cm3 mokcuk-' s-l a& \_+OH + CS2 = (1 .I35 2 0.34) X lOmu cm3 molecu!e-' s-