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A reinvestigation of the Cl + ClONO2 reaction by flash photolysis resonance fluorescence

โœ Scribed by Michael J. Kurylo; Geoffrey L. Knable; Jennifer L. Murphy


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
400 KB
Volume
95
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The reaction of Cl atoms with chlorine nitrate has been reinvestigated by flash photolysis resonance fluorcsccnce over the temperature range 220-296 I;. The new results can be tit to the Arrhenius expression kr = 7.3 X 10-r* esp(165/7I cm3 molecule-' s-l, in good agreement with another recent study but significantly different from our earlier work. Reasons for these differences are suggested and their sigrificance discussed.


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