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Five-coordinate hydrido / olefin platinum(II) complexes

✍ Scribed by Vincenzo De Felice; Maria Luisa Ferrara; Achille Panunzi; Francesco Ruffo


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
175 KB
Volume
439
Category
Article
ISSN
0022-328X

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Five-coordinate complexes [PtX 2 (olefin)(2,9-Me 2 -phen)] (1; chloride ions in axial positions. The iodo complexes 1(a-c)z are not oxidized by iodine even under UV irradiation but 2,9-Me 2 -phen = 2,9-dimethyl-1,10-phenanthroline; olefin = ethene denoted by a, propene by b, 1-butene by c; X = Cl re