New cationic five-coordinate monoolefin hydrocarbyl complexes of platinum(II)
✍ Scribed by Angeles Sanchez; Carlo Castellari; Achille Panunzi; Aldo Vitagliano; Vincenzo De Felice
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 642 KB
- Volume
- 388
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Five-coordinate complexes [PtX 2 (olefin)(2,9-Me 2 -phen)] (1; chloride ions in axial positions. The iodo complexes 1(a-c)z are not oxidized by iodine even under UV irradiation but 2,9-Me 2 -phen = 2,9-dimethyl-1,10-phenanthroline; olefin = ethene denoted by a, propene by b, 1-butene by c; X = Cl re
## Abstract New platinum complexes of the type __cis__‐Pt(L)~2~Cl~2~ have been synthesized from five‐ and six‐membered cyclic phosphines, which were prepared after deoxygenating a series of phosphine oxides (3‐phospholene oxides, phospholane oxides, a 1,4‐dihydrophosphinine oxide, and a 1,2,3,6‐tet