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Five- and six-coordinate hydrido(carbonyl)-ruthenium(II) and -osmium(II) complexes containing triisopropylphosphine as ligand

✍ Scribed by M.A. Esteruelas; H. Werner

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
722 KB
Volume
303
Category
Article
ISSN
0022-328X

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Ruthenium complexes I Osmium complexes I Insertion reactions I Carbon disulfide I Carbon dioxide I Methyl isothiocyanate I Zwitterionic ligands The five-coordinate chloro(hydrido)-and hydrido(iod0)ruthenium(I1) and -osmium(II) compounds [MHX(CO)(PiPr&] (1, 2, 6, 7) react with CS2 to give the octahed