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New ruthenium(II) hydrido-carbonyl and carbonyl complexes containing triphenylphosphine

✍ Scribed by B.R. James; L.D. Markham


Publisher
Elsevier Science
Year
1971
Weight
145 KB
Volume
7
Category
Article
ISSN
0020-1650

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Hydrido(carbonyl) and Hydrido(carbene) C
✍ Helmut Werner; Wolfram StΓΌer; Birgit WeberndΓΆrfer; Justin Wolf πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 353 KB πŸ‘ 2 views

The five-coordinate compound [RuHCl(CO)(PiPr 2 Ph) 2 ] (1), [RuHCl 2 (CO)(PiPr 2 Ph) 2 ] -contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH 2 bond which was prepared from RuCl 3 β€’ 3 H 2 O and PiPr 2 Ph in methanol in the presence of NEt 3 , reacts with CO and wit