Hydrido(carbonyl) and Hydrido(carbene) C
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Helmut Werner; Wolfram StΓΌer; Birgit WeberndΓΆrfer; Justin Wolf
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Article
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1999
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John Wiley and Sons
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English
β 353 KB
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The five-coordinate compound [RuHCl(CO)(PiPr 2 Ph) 2 ] (1), [RuHCl 2 (CO)(PiPr 2 Ph) 2 ] -contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH 2 bond which was prepared from RuCl 3 β’ 3 H 2 O and PiPr 2 Ph in methanol in the presence of NEt 3 , reacts with CO and wit