Manganese(II) complex of the ‘tripod’ ligand tris(2-benzimidazolylmethyl)amine. Five-coordinate and six-coordinate Mn(II) in the crystal structure
✍ Scribed by Aderemi R. Oki; Prasad R. Bommarreddy; Hongming Zhang; Narayan Hosmane
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 478 KB
- Volume
- 231
- Category
- Article
- ISSN
- 0020-1693
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## Abstract The five‐coordinate compounds [MHCl(CO)(P__i__Pr~3~)~2~] (where 1a: M = Ru; 1b: M = Os) react with P__i__Pr~2~R\* [where R\* = CH(Me)Ph] to give the octahedral complexes __mer__‐[MHCl(CO)(P__i__Pr~2~R\*)~3~] (6 and 7). The lability of the phosphane __trans__ to the hydride is illustrate
## Abstract The stability constants of the Cu^II^ chelates with the tripodal heptadentate ligand tris{2‐[(2‐pyridylmethyl)amino]ethyl}amine (=__N__′‐(pyridin‐2‐ylmethyl)‐__N,N__‐bis{2‐[(pyridin‐2‐ylmethyl)amino]ethyl}ethane‐1,2‐diamine; tpaa), determined by potentiometry and UV spectrometry, show t
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