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Six-Coordinate Ruthenium(II) Complexes Containing Unsymmetrical 1,2-Bis(phosphanyl)ethanes and 1-Arsanyl-2-phosphanylethanes as Ligands

✍ Scribed by Guido Fries; Kerstin Ilg; Matthias Pfeiffer; Dietmar Stalke; Helmut Werner

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 313 KB
Volume: 2000
Category: Article
ISSN: 1434-1948
DOI: 10.1002/1099-0682(200012)2000:12<2597::aid-ejic2597>3.0.co;2-f

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✦ Synopsis

The bis(η 3 -2-methallyl)ruthenium (II) 1) and the unsymmetrical 1,2-bis-(phosphanyl)ethanes Ph 2 PCH 2 CH 2 PR 2 . The As,P analogue [Ru(η 3 -2-MeC 3 H 4 ) 2 (κ 2 -Ph 2 PCH 2 CH 2 AstBu 2 )] (4) was obtained by the same route. The reaction of 2 with hexafluoroacetylacetone afforded the chelate compound [Ru(κ 2 -[F 6 ]- [a]

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