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A Novel Anionic Five-Coordinate Tris(trichlorostannato)platinum(II) Complex

✍ Scribed by Prof. Alberto Albinati; Ralph Nägeli; Heinz Rüegger; Priv.-Doz. Dr. Paul S. Pregosin


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
217 KB
Volume
21
Category
Article
ISSN
0044-8249

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Five-coordinate complexes [PtX 2 (olefin)(2,9-Me 2 -phen)] (1; chloride ions in axial positions. The iodo complexes 1(a-c)z are not oxidized by iodine even under UV irradiation but 2,9-Me 2 -phen = 2,9-dimethyl-1,10-phenanthroline; olefin = ethene denoted by a, propene by b, 1-butene by c; X = Cl re