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First Diastereoselective Chiral Synthesis of (-)-Securinine (I).

โœ Scribed by Toshio Honda; Hidenori Namiki; Kyosuke Kaneda; Hirotake Mizutani

Book ID
101951841
Publisher
John Wiley and Sons
Year
2004
Weight
53 KB
Volume
35
Category
Article
ISSN
0931-7597

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First Diastereoselective Asymmetric Carbometallation of Chiral Vinyl Metals. -Reaction of (Z) metalated allyl amines such as (I) bearing a chiral aromatic amine moiety with substituted allylic zinc reagents is face-selective providing ฮฒ-methylated amines (III) with good diastereoselectivity.