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First diastereoselective asymmetric carbometallation of chiral vinyl metals

✍ Scribed by Denis Brasseur; Hadi Rezaei; Alain Fuxa; Alexandre Alexakis; Pierre Mangeney; Ilan Marek; Jean F. Normant

Book ID
104259457
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
173 KB
Volume
39
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: First Diastereosele
ChemInform Abstract: First Diastereoselective Asymmetric Carbometallation of Chiral Vinyl Metals.
✍ D. BRASSEUR; H. REZAEI; A. FUXA; A. ALEXAKIS; P. MANGENEY; I. MAREK; J. F. NORMA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 2 views

First Diastereoselective Asymmetric Carbometallation of Chiral Vinyl Metals. -Reaction of (Z) metalated allyl amines such as (I) bearing a chiral aromatic amine moiety with substituted allylic zinc reagents is face-selective providing Ξ²-methylated amines (III) with good diastereoselectivity.