𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Diastereoselective Carbometalation of γ-Heterosubstituted Vinyl Metals.

✍ Scribed by I. MAREK; J.-M. LEFRANCOIS; J. F. NORMANT

Book ID
112021964
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
26
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: First Diastereosele
ChemInform Abstract: First Diastereoselective Asymmetric Carbometallation of Chiral Vinyl Metals.
✍ D. BRASSEUR; H. REZAEI; A. FUXA; A. ALEXAKIS; P. MANGENEY; I. MAREK; J. F. NORMA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

First Diastereoselective Asymmetric Carbometallation of Chiral Vinyl Metals. -Reaction of (Z) metalated allyl amines such as (I) bearing a chiral aromatic amine moiety with substituted allylic zinc reagents is face-selective providing β-methylated amines (III) with good diastereoselectivity.