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ChemInform Abstract: Diastereoselective Carbometalation of Vinylmetals.

โœ Scribed by I. MAREK; J.-M. LEFRANCOIS; J.-F. NORMANT

Book ID
112020745
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: First Diastereosele
ChemInform Abstract: First Diastereoselective Asymmetric Carbometallation of Chiral Vinyl Metals.
โœ D. BRASSEUR; H. REZAEI; A. FUXA; A. ALEXAKIS; P. MANGENEY; I. MAREK; J. F. NORMA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 2 views

First Diastereoselective Asymmetric Carbometallation of Chiral Vinyl Metals. -Reaction of (Z) metalated allyl amines such as (I) bearing a chiral aromatic amine moiety with substituted allylic zinc reagents is face-selective providing ฮฒ-methylated amines (III) with good diastereoselectivity.