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Diastereoselective β-elimination. Synthesis of chiral alkoxy-allenes

✍ Scribed by A. Alexakis; P. Mangeney; J.F. Normant


Book ID
104229142
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
223 KB
Volume
26
Category
Article
ISSN
0040-4039

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Synthesis of chiral β -alkoxy- α,β -unsa
✍ André Lubineau; Annie Malleron 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 153 KB

The title compounds are synthesized in one-pot from the easily available sodium salts of unsymmetrical 1,3\_dicarbonyl derivatives and chiral alkoxides. Die&.-Alder additions still play a major role in preparative organic chemistry and asymmetric induction in such reactions represents a challenge i