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First Anhydrous Gold Perchlorato Complex: ClO2Au(ClO4)4. Synthesis and Molecular and Crystal Structure Analysis.

โœ Scribed by Frederique Cunin; Catherine Deudon; Frederic Favier; Bernard Mula; Jean Louis Pascal


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
33
Category
Article
ISSN
0931-7597

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Single crystals of Lu(ClO 4 ) 3 ยด3 H 2 O were obtained by slow dehydration of Lu(ClO 4 ) 3 ยด6 H 2 O at 140 ยฐC under flowing argon. The compound crystallizes in the triclinic crystal system (P1, Z = 2, a = 750.3(1), b = 838.4(1), c = 1054.6(2) pm, a = 79.77(2)ยฐ, b = 79.18(2), c = 63.83(2), R all = 0.

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Synthesis, spectroscopy, and crystal structures of [Cu(ca 2 en) 2 ]ClO 4 (1) and [Cu(ca 2 en)(PPh 3 ) 2 ]ClO 4 (2) (ca 2 en N,N'-bis(trans-cinnamaldehyde)ethylenediimine) are reported. Compound 1 crystallizes in the orthorhombic space group Pbca, with a 12.5647( ), b 21.8203(11), c 27.992(2) รค, V 76