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Facile synthesis of amino bicyclo[2.2.1]heptyl alcohol and its application for enantioselective additions of diethylzinc to aldehydes

✍ Scribed by Naoto Hanyu; Takashi Mino; Masami Sakamoto; Tsutomu Fujita

Book ID
108379790
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
124 KB
Volume
41
Category
Article
ISSN
0040-4039

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## Abstract β‐Amino alcohols derived from (1__R__,2__S__)‐norephedrine were synthesized and used as ligands in the catalytic enantioselective diethylzinc addition to benzaldehydes. __N__‐alkylated (1__R__,2__S__)‐norephedrine‐based derivative 3a gave the highest enantioselectivity. The effects of d