Facile Enantioselective Ring-Opening Reaction of meso Epoxides with Anilines Using (S)-(–)-BINOL-Ti Complex as a Catalyst
✍ Scribed by Rukhsana I. Kureshy; Surendra Singh; Noor-ul H. Khan; Sayed H. R. Abdi; Eringathodi Suresh; Raksh V. Jasra
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 137 KB
- Volume
- 2006
- Category
- Article
- ISSN
- 1434-193X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract Catalyzed by the Mg complexes of BINOL derivatives, the enantioselective ring opening reaction of various __meso__‐epoxides proceeded smoothly with either aromatic or aliphatic amines as the nucleophiles to afford the corresponding chiral β‐amino alcohols in moderate‐to‐high yields with
## Abstract The reaction with anilines is catalyzed by the (R)‐BINOL/Bu~2~Mg/MeLi system and tolerates a wide range of functional groups [cf.