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Enantioselective Ring Opening Reaction of meso-Epoxides with Aromatic and Aliphatic Amines Catalyzed by Magnesium Complexes of BINOL Derivatives

✍ Scribed by Hongli Bao; Jiang Wu; Hongji Li; Zheng Wang; Tianpa You; Kuiling Ding

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
258 KB
Volume
2010
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

Catalyzed by the Mg complexes of BINOL derivatives, the enantioselective ring opening reaction of various meso‐epoxides proceeded smoothly with either aromatic or aliphatic amines as the nucleophiles to afford the corresponding chiral β‐amino alcohols in moderate‐to‐high yields with good to excellent enantioselectivities.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.