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Enantioselective Ring Opening of meso-Epoxides with Tetrachlorosilane Catalyzed by Chiral Bipyridine N,N′-Dioxide Derivatives.

✍ Scribed by Makoto Nakajima; Makoto Saito; Michinao Uemura; Shunichi Hashimoto


Publisher
John Wiley and Sons
Year
2003
Weight
106 KB
Volume
34
Category
Article
ISSN
0931-7597

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Asymmetric Ring Opening of meso-Epoxides
✍ Bo Gao; Yuehong Wen; Zhigang Yang; Xiao Huang; Xiaohua Liu; Xiaoming Feng 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 242 KB 👁 2 views

## Abstract The catalytic asymmetric ring opening of __meso__‐epoxides with aromatic amines was achieved using a new proline‐based __N__,__N′__‐dioxide‐indium tris(triflate) complex in high yields (up to 99%) with excellent enantioselectivities (up to 99% __ee__) under mild conditions. The coordina