## Abstract Catalyzed by the Mg complexes of BINOL derivatives, the enantioselective ring opening reaction of various __meso__‐epoxides proceeded smoothly with either aromatic or aliphatic amines as the nucleophiles to afford the corresponding chiral β‐amino alcohols in moderate‐to‐high yields with
Microwave-Assisted Asymmetric Ring Opening of meso-Epoxides with Aromatic Amines Catalyzed by a Ti—(S)-(-)-BINOL Complex.
✍ Scribed by Rukhsana I. Kureshy; Surendra Singh; Noor-ul H. Khan; Sayed H. R. Abdi; Santosh Agrawal; Vishal J. Mayani; Raksh V. Jasra
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 18 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
## Abstract The reaction with anilines is catalyzed by the (R)‐BINOL/Bu~2~Mg/MeLi system and tolerates a wide range of functional groups [cf.
## Abstract The catalytic asymmetric ring opening of __meso__‐epoxides with aromatic amines was achieved using a new proline‐based __N__,__N′__‐dioxide‐indium tris(triflate) complex in high yields (up to 99%) with excellent enantioselectivities (up to 99% __ee__) under mild conditions. The coordina