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Enantioselective Ring-Opening Reaction of meso-Epoxides with ArSH Catalyzed by a C2-Symmetric Chiral Bipyridyldiol-Titanium Complex.

✍ Scribed by Yi-Jing Chen; Chinpiao Chen


Publisher
John Wiley and Sons
Year
2007
Weight
22 KB
Volume
38
Category
Article
ISSN
0931-7597

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Enantioselective Ring Opening Reaction o
✍ Hongli Bao; Jiang Wu; Hongji Li; Zheng Wang; Tianpa You; Kuiling Ding πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 258 KB

## Abstract Catalyzed by the Mg complexes of BINOL derivatives, the enantioselective ring opening reaction of various __meso__‐epoxides proceeded smoothly with either aromatic or aliphatic amines as the nucleophiles to afford the corresponding chiral β‐amino alcohols in moderate‐to‐high yields with