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Catalytic Asymmetric Ring-Opening Reaction of meso-Epoxides with Aryl Selenols and Thiols Catalyzed by a Heterobimetallic Gallium-Titanium-Salen Complex

✍ Scribed by Jiangtao Sun; Minghua Yang; Fang Yuan; Xuefeng Jia; Xia Yang; Yi Pan; Chengjian Zhu


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
234 KB
Volume
351
Category
Article
ISSN
1615-4150

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Asymmetric Ring Opening of meso-Epoxides
✍ Bo Gao; Yuehong Wen; Zhigang Yang; Xiao Huang; Xiaohua Liu; Xiaoming Feng 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 242 KB

## Abstract The catalytic asymmetric ring opening of __meso__‐epoxides with aromatic amines was achieved using a new proline‐based __N__,__N′__‐dioxide‐indium tris(triflate) complex in high yields (up to 99%) with excellent enantioselectivities (up to 99% __ee__) under mild conditions. The coordina