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fac-Tris­(di­methyl­form­amide)­tris­(iso­thio­cyanato)­iron(III)

✍ Scribed by Wang, Ming-Sheng ;Cai, Li-Zhen ;Guo, Guo-Cong ;Huang, Jin-Shun


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
280 KB
Volume
59
Category
Article
ISSN
1600-5368

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In the title compound, (C 4 H 12 N 2 )[Ti(C 7 H 4 O 3 ) 3 ]ÁH 2 OÁ-C 3 H 7 NO, the Ti IV atom is chelated by three salicylate ligands in an octahedral geometry, the complex anion being the fac isomer. The cations, complex anions and solvent molecules are linked by hydrogen bonds into a layer structu