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Experiments and Calculations on Rate Coefficients for Pyrolysis of SO 2 and the Reaction O + SO at High Temperatures

✍ Scribed by Lu, Chih-Wei; Wu, Yu-Jong; Lee, Yuan-Pern; Zhu, R. S.; Lin, M. C.

Book ID: 126857228
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 228 KB
Volume: 107
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp036025c

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📜 SIMILAR VOLUMES

Rate constants at 298 k for the reaction

Rate constants at 298 k for the reactions SO+SO+M→(SO)2+M AND SO+(SO)2→SO2+S2O

✍ John T. Herron; Robert E. Huie 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 255 KB

The decay of SO generated in the reaction 0 r0CS-r CO+ SO in the absence of O1 has been studied at 298 K from 2 to 8 Torr, using a tubular Row reactor coupled to a mass spectrometer. The products of the decay of SO are S. SO:. S20. and (SO),. The kinetics of tile decay of SO could be accounted for o

Measurements of the bimolecular rate con

Measurements of the bimolecular rate constants for S + O2 → SO + O and CS2 + O2 → CS + SO2 at high temperatures

✍ Ko Saito; Yuji Ueda; Reiko Ito; Terumitsu Kakumoto; Akira Imamura 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 580 KB

The bimolecular reactions in the title were measured behind shock waves by monitoring the 0-atom production in COS-02-Ar and CS2-02-Ar mixtures over the temperature range between 1400 and 2200 K. A value of the rate constant for S + O2 -+ SO f 0 was evaluated to be (3.8 2 0.7) x 10" cm3 mol-' s-' be

Rate coefficients at 298 K for SO reacti

Rate coefficients at 298 K for SO reactions with O2, O3, and NO2

✍ G. Black; R.L. Sharpless; T.G. Slanger 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 271 KB

Rcccivcd 30 Apnl 1982 SO:, photodissociation at 193 nm (AIF cxclmer lmr) ha been used to create SO radicals; the chcmdumincsccncc from the SO + 03 reaction has been used to follow the SO ndical decay. Rate coefticicnls at 298 K of (1 07 t 0.16) x 10-r6, (1 06 f 0 16) x 10-r3, and (1 48 k 0 20) x IO-

Oxidation of S and SO by O2 in high-temp

Oxidation of S and SO by O2 in high-temperature pyrolysis and photolysis reaction systems

✍ D. Woiki; P. Roth 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 718 KB

## Abstract The reaction of S atoms with O~2~ was studied behind reflected shock waves applying atomic resonance absorption spectroscopy (ARAS) for concentration measurements of S and O atoms. S atoms were generated either by laser‐flash photolysis (LFP) of CS~2~ or by the high‐temperature pyrolysi

Rate coefficients for so reactions with

Rate coefficients for so reactions with O2 and O3 over the temperature range 230 to 420 K

✍ G. Black; R.L. Sharpless; T.G. Slanger 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 353 KB

The mechanism of SO2 oxidation by CH3O2

The mechanism of SO2 oxidation by CH3O2 radicals. Rate coefficients for the reactions of CH3O2 with SO2 and NO

✍ R. Simonaitis; J. Heicklen 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 237 KB

The reacttonsof CH30z nitIt SO2 and NO haw been studied bv steady state photo&s of azomethane in the presence of Ot-SOz-SO mixtures at 196 M and I ;Ltm total pressure. Thr quantum yield of NO otidntion by CHxO= m.dicxG is increased substanthlIy when SO? is added ro the system indicating an SOa induc