𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Experimental and theoretical studies of the vibrations and structure of 2,2,2-trifluoroethyl trifluoroacetate, CF3CO2CH2CF3

✍ Scribed by María Eliana Defonsi Lestard; María Eugenia Tuttolomondo; Eduardo Lelio Varetti; Derek A. Wann; Heather E. Robertson; David W.H. Rankin; Aida Ben Altabef

Book ID
108212990
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
544 KB
Volume
917
Category
Article
ISSN
0022-2860

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A kinetic study of the reaction of fluor
A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K
✍ Timothy J. Wallington; Michael D. Hurley; Jichun Shi; M. Matti Maricq; Jens Sehe 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 807 KB

A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.

Substituent effects on the disproportion
Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. IV. Reactions of ·CF3 + CF3CH2CF2· and CF3CH2CF2· + CF3CH2CF2·
✍ Shane R. Smith; Bert E. Holmes 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB 👁 2 views

Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 Ϯ 2 K, have been measured as 0.034 Ϯ 0.009 for the collision between CF 3 CH 2 CF 2 ϩ CF 3 radicals and as 0.075 Ϯ 0.019 for CF 3 CH 2 CF 2 ϩ CF 3 CH 2 CF 2 radicals. The effect of the two fluori