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Experimental and theoretical structure and vibrational analysis of ethyl trifluoroacetate, CF3CO2CH2CH3

✍ Scribed by María Eliana Defonsi Lestard; María Eugenia Tuttolomondo; Derek A. Wann; Heather E. Robertson; David W. H. Rankin; Aida Ben Altabef

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
230 KB
Volume
41
Category
Article
ISSN
0377-0486

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The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine

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## Abstract The intermolecular interaction energy curves of CH~3~OCH~3~CH~2~F~2~, CF~3~OCH~3~CH~2~F~2~, CF~3~OCF~3~CH~2~F~2~, CH~3~OCH~3~CHF~3~, CF~3~OCH~3~CHF~3~, and CF~3~OCF~3~CHF~3~ complexes were calculated by the MP2 level __ab initio__ molecular orbital method using the 6‐311G\*\* basi