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Excimer formation in triplet-triplet annihilation reactions of metal (3ππ*) porphyrins and (3ππ*) phthalocyanines

✍ Scribed by Mark E. Frink; G. Ferraudi

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
269 KB
Volume
124
Category
Article
ISSN
0009-2614

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✦ Synopsis

The triplet-triplet annihilation of the lowest-lying excited states of porphyrins and phthalocyanines has been investigated by laser flash photolysis. Spectroscopic and kinetic evtdence indicates that the lowest-lying triplet dimerizes into excimers at a rate less than diffusion controlled.

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