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Reversible Formation of Iodosylbenzene–Iron Porphyrin Intermediates in the Reaction of Oxoiron(IV) Porphyrin π-Cation Radicals and Iodobenzene

✍ Scribed by Wonwoo Nam; Sun Kyung Choi; Mi Hee Lim; Jan-Uwe Rohde; Inwoo Kim; Jinheung Kim; Cheal Kim; Lawrence Que; Jr.

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
109 KB
Volume
115
Category
Article
ISSN
0044-8249

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## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford

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