The rotationally resolved emission spectra of NH(c 'n) was observed in the vacuum UV photolysis of ammonia by Ar, Kr and H resonance lines. Hot rotational distribution was reconfirmed for photolysis by either the Kr or the H line, while, in the case of Ar, NH(c 'II) was found to be cold. From the ma
Formation of NH(c1Π), NH(A 3Π) and NCO(A 2Σ) in the VUV photolysis of HNCO
✍ Scribed by Kenkichi Uno; Takumi Hikida; Atsunari Hiraya; Kosuke Shobatake
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 395 KB
- Volume
- 166
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Photodissociative
excitation processes of gaseous HNCO are studied in the wavelength region 107-180 nm using synchrotron radiation as a light source. Fluorescence excitation spectra of the photofragments, NH (c a, A 'IT) and NC0 (A '2 ), are measured under near collision-free conditions. The quantum yields for formation of these excited radicals are also determined.
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