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Excess enthalpies and excess heat capacities of (N,N-dimethylformamide + tetrahydrofuran + cyclohexane) at the temperature 298.15 K

✍ Scribed by G. Conti; P. Gianni; E. Matteoli


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
212 KB
Volume
26
Category
Article
ISSN
0021-9614

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✦ Synopsis


Excess enthalpies and excess heat capacities at the temperature (298.15 \mathrm{~K}) were determined for (\left{x \mathrm{HCON}\left(\mathrm{CH}{3}\right){2}+(1-x) c-\left(\mathrm{CH}{2}\right){4} \mathrm{O}\right}) and for (\left{x_{1} \mathrm{HCON}\left(\mathrm{CH}{3}\right){2}+x_{2} c-\left(\mathrm{CH}{2}\right){4} \mathrm{O}+\right.) ( (\left.\left.1-x_{1}-x_{2}\right) c-\mathrm{C}{6} \mathrm{H}{12}\right}). Both experimental properties were described through an empirical equation. Enthalpies were also described through UNIQUAC and UNIFAC models. The ternary mixture behaves very similarly to the other ternary mixture, previously studied, in which (c-\left(\mathrm{CH}{2}\right){4} \mathrm{O}) was replaced by (\mathrm{C}{2} \mathrm{H}{5} \mathrm{OH})


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## Excess molar enthalpies of {x1CH3OH , measured with an isothermal dilution calorimeter at the temperature 298.15 K, are reported. The experimental values have been analyzed with a mole-fraction association model having binary and ternary parameters.

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The excess enthalpies H E m of [x {BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl}+(1x){CH3(CH2)5CH3 or CH3(CH2)14CH3 or c-(CH2)6} have been measured at the temperature 298.15 K. Mixing was endothermic at all x and the H E m s were found to vary in the sequence: BrCH2CH2Cl q BrCH2Cl q Br