Excess molar enthalpies and excess molar heat capacities at T = 298.15 K were determined for {xCHCl3 Both experimental properties were represented by a Redlich-Kister type equation. The large negative values of the excess enthalpies and the positive values of the excess heat capacities observed in
Excess enthalpies and excess heat capacities of (N,N-dimethylformamide + tetrahydrofuran + cyclohexane) at the temperature 298.15 K
β Scribed by G. Conti; P. Gianni; E. Matteoli
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 212 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
β¦ Synopsis
Excess enthalpies and excess heat capacities at the temperature (298.15 \mathrm{~K}) were determined for (\left{x \mathrm{HCON}\left(\mathrm{CH}{3}\right){2}+(1-x) c-\left(\mathrm{CH}{2}\right){4} \mathrm{O}\right}) and for (\left{x_{1} \mathrm{HCON}\left(\mathrm{CH}{3}\right){2}+x_{2} c-\left(\mathrm{CH}{2}\right){4} \mathrm{O}+\right.) ( (\left.\left.1-x_{1}-x_{2}\right) c-\mathrm{C}{6} \mathrm{H}{12}\right}). Both experimental properties were described through an empirical equation. Enthalpies were also described through UNIQUAC and UNIFAC models. The ternary mixture behaves very similarly to the other ternary mixture, previously studied, in which (c-\left(\mathrm{CH}{2}\right){4} \mathrm{O}) was replaced by (\mathrm{C}{2} \mathrm{H}{5} \mathrm{OH})
π SIMILAR VOLUMES
## Ε½ . Ε½ . 4 x c-CH O q 1 y x y x c-C H . The experimental data were described through a 2 24 1 2 6 1 2 RedlichαKister type equation. The ternary mixtures exhibit large positive deviations for both properties investigated. Ternary H E and C E data were poorly predicted by rules which m p, m empiri
## Excess molar enthalpies of {x1CH3OH , measured with an isothermal dilution calorimeter at the temperature 298.15 K, are reported. The experimental values have been analyzed with a mole-fraction association model having binary and ternary parameters.
The excess enthalpies H E m of [x {BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl}+(1x){CH3(CH2)5CH3 or CH3(CH2)14CH3 or c-(CH2)6} have been measured at the temperature 298.15 K. Mixing was endothermic at all x and the H E m s were found to vary in the sequence: BrCH2CH2Cl q BrCH2Cl q Br