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Excess enthalpies of (tetrahydrofuran or tetrahydropyran + an n-alkane) at the temperature 298.15 K

✍ Scribed by I. Castro; M. Pintos; A. Amigo; R. Bravo; M.I.Paz Andrade


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
122 KB
Volume
26
Category
Article
ISSN
0021-9614

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Excess enthalpies of (a bromochloroalkan
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The excess enthalpies H E m of [x {BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl}+(1x){CH3(CH2)5CH3 or CH3(CH2)14CH3 or c-(CH2)6} have been measured at the temperature 298.15 K. Mixing was endothermic at all x and the H E m s were found to vary in the sequence: BrCH2CH2Cl q BrCH2Cl q Br

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Excess enthalpies and excess heat capacities at the temperature \(298.15 \mathrm{~K}\) were determined for \(\left\{x \mathrm{HCON}\left(\mathrm{CH}_{3}\right)_{2}+(1-x) c-\left(\mathrm{CH}_{2}\right)_{4} \mathrm{O}\right\}\) and for \(\left\{x_{1} \mathrm{HCON}\left(\mathrm{CH}_{3}\right)_{2}+x_{2}

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Flow-microcalorimetric measurements of excess molar enthalpies at the temperaturc \(298.15 \mathrm{~K}\) are reported for \(\left\{x \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{C}\left(\mathrm{CH}_{3}\right)_{2} \mathrm{OCH}_{3}+(1-x) \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2 v+4} \mathrm{CH}_{3}\rig

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Excess enthalpies for (aniline+pentane or 2-methylpentane or cyclohexane or hexane or octane or decane) as well as of (aniline+cyclohexene or hex-1-ene or oct-1-ene) were measured at the temperature 363.15 K and pressure 1.89 MPa with the help of an isothermal flow calorimeter from Hart Scientific (