Excess enthalpies of (aniline + an alkane or an alkene) at the temperature 363.15 K
✍ Scribed by Garabed Avedis; Bärbel Meents; Jürgen Gmehling
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 376 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
✦ Synopsis
Excess enthalpies for (aniline+pentane or 2-methylpentane or cyclohexane or hexane or octane or decane) as well as of (aniline+cyclohexene or hex-1-ene or oct-1-ene) were measured at the temperature 363.15 K and pressure 1.89 MPa with the help of an isothermal flow calorimeter from Hart Scientific (model 7501). For all the mixtures endothermic mixing was observed. 71995 Academic Press Limited.
📜 SIMILAR VOLUMES
Excess molar enthalpies of \(\left\{x_{1} \mathrm{CH}_{3} \mathrm{OH}+x_{2} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}+\left(1-x_{1}-x_{2}\right) \mathrm{CH}_{3} \mathrm{OCH}_{3}\right\}\), measured with a flow microcalorimeter at the temperature \(298.15 \mathrm{~K}\), are reported. The experime
The excess enthalpies H E m of [x {BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl}+(1x){CH3(CH2)5CH3 or CH3(CH2)14CH3 or c-(CH2)6} have been measured at the temperature 298.15 K. Mixing was endothermic at all x and the H E m s were found to vary in the sequence: BrCH2CH2Cl q BrCH2Cl q Br
Flow-microcalorimetric measurements of excess molar enthalpies at the temperaturc \(298.15 \mathrm{~K}\) are reported for \(\left\{x \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{C}\left(\mathrm{CH}_{3}\right)_{2} \mathrm{OCH}_{3}+(1-x) \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2 v+4} \mathrm{CH}_{3}\rig