Excess enthalpies for (methanol + methyl ethanoate + cyclohexane) and (methanol + tetrachloromethane + cyclohexane) at the temperature 298.15 K
โ Scribed by Isamu Nagata
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 355 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0021-9614
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โฆ Synopsis
Excess molar enthalpies of {x1CH3OH
, measured with an isothermal dilution calorimeter at the temperature 298.15 K, are reported. The experimental values have been analyzed with a mole-fraction association model having binary and ternary parameters.
๐ SIMILAR VOLUMES
Excess molar enthalpies of \(\left\{x_{1} \mathrm{CH}_{3} \mathrm{OH}+x_{2} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}+\left(1-x_{1}-x_{2}\right) \mathrm{CH}_{3} \mathrm{OCH}_{3}\right\}\), measured with a flow microcalorimeter at the temperature \(298.15 \mathrm{~K}\), are reported. The experime
The (liquid + liquid) equilibria of (x1C6H5NH2 at the temperature 298.15 K have been measured. The experimental values have been well correlated with extended UNIQUAC and modified Wilson models having binary, ternary, and quaternary parameters.
The excess enthalpies H E m of [x {BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl}+(1x){CH3(CH2)5CH3 or CH3(CH2)14CH3 or c-(CH2)6} have been measured at the temperature 298.15 K. Mixing was endothermic at all x and the H E m s were found to vary in the sequence: BrCH2CH2Cl q BrCH2Cl q Br
Excess molar enthalpies and excess molar heat capacities at T = 298.15 K were determined for {xCHCl3 Both experimental properties were represented by a Redlich-Kister type equation. The large negative values of the excess enthalpies and the positive values of the excess heat capacities observed in
Excess enthalpies and excess heat capacities at the temperature \(298.15 \mathrm{~K}\) were determined for \(\left\{x \mathrm{HCON}\left(\mathrm{CH}_{3}\right)_{2}+(1-x) c-\left(\mathrm{CH}_{2}\right)_{4} \mathrm{O}\right\}\) and for \(\left\{x_{1} \mathrm{HCON}\left(\mathrm{CH}_{3}\right)_{2}+x_{2}