Evaluation of Chiral Bidentate Ligand—Metal Complexes in Asymmetric 1,3-Dipolar Cycloaddition Reaction of Nitrones with 3-Alkenoyl-2-oxazolidinones.
✍ Scribed by Takao Saito; Takuya Yamada; Shingo Miyazaki; Takashi Otani
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 28 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Using the __C__~2~‐symmetric bis‐oxazoline copper(II) catalyst **6f** as a chiral Lewis acid, α′‐phosphoric enones **2** undergo 1,3‐dipolar cycloaddition with nitrones **3** to provide isoxazolidines **4** with very high enantioselectivity and __endo/exo__ selectivity.
## Abstract Ruthenium complexes of formula [(η^6^‐arene)Ru(LL\*)(H~2~O)][SbF~6~]~2~ (arene = C~6~H~6~, __p__‐MeC~6~H~4~__i__Pr, C~6~Me~6~; LL\* = bidentate chelate chiral ligand with PN, PP or NN donor atoms) have been tested as catalyst precursors for the asymmetric 1,3‐dipolar cycloaddition of ni
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v