Asymmetric 1,3-Dipolar Cycloaddition Reaction of Nitrones and Acrolein with a Bis-Titanium Catalyst as Chiral Lewis Acid.
β Scribed by Taichi Kano; Takuya Hashimoto; Keiji Maruoka
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 29 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract Using the __C__~2~βsymmetric bisβoxazoline copper(II) catalyst **6f** as a chiral Lewis acid, Ξ±β²βphosphoric enones **2** undergo 1,3βdipolar cycloaddition with nitrones **3** to provide isoxazolidines **4** with very high enantioselectivity and __endo/exo__ selectivity.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v