molecules from a discharge have been analyzed by the emission of the infrared atmospheric (0.0) bancfat 12700 A and by the emission of the atmospheric (0,O) band at 7619 A due to the energy pooling reaction ## 202(1Agj -+02('Cs) + 02(%;) . Particular rate constants for the deactivation of 02(1 A
ETON 2: Quenching parameters for the proposed precursors of O2(b1Σg+) and O(1S) in the terrestrial nightglow
✍ Scribed by I.C. McDade; D.P. Murtagh; R.G.H. Greer; P.H.G. Dickinson; G. Witt; J. Stegman; E.J. Llewellyn; L. Thomas; D.B. Jenkins
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 1005 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0032-0633
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The generation of metastable O, ('Xg+) and Oz('Ag) in the H + 0, system of reactions was studied by the flow discharge chemiluminescence detection method. In addition to the Oz('Pg') and Oz(' , H0,(2A~oo) + H02(2AlohO), H02(zA~o,) + HO,(zA~oo), and H Oz(2A~oo) --+ H0,(2A&,o) emissions were detected
Absolute rate constants for the quenching of metastable 02@lCi) by acetylene. ethylene. propylene. butene-1, tmns-butene-2, cis-butene-2, and tetramethylethylene were determined at 300%. The rate constants range from 4 to 10 X 10 -13cm3molecule-lsec-I, and exhibit a systematic variation with molecu