Temperature dependence of the collisional quenching of singlet molecular oxygen (O2(a1Δg) and O2(b1Σg+)) by SO2
✍ Scribed by Razmik B. Boodaghians; Patricia M. Borrell; Peter Borrell
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 547 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0047-2670
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molecules from a discharge have been analyzed by the emission of the infrared atmospheric (0.0) bancfat 12700 A and by the emission of the atmospheric (0,O) band at 7619 A due to the energy pooling reaction ## 202(1Agj -+02('Cs) + 02(%;) . Particular rate constants for the deactivation of 02(1 A
In a fast flow system mixtures of SOCI 2 with helium were passed through a microwave discharge and added downstream to a flow of metastable 02 (lAg) molecules. Chemiluminescence of the SO(IAg--aZg) (0,0) band was observed at 1.705 #m in addition to the already known (0,0), (0,1), (1,1), and (2,2) ba
The rate constants for collisional quenching of Oz(b 'x:) by COz, NzO. NO, NHs\_ HCl and SOz. and of Oz(a '+.I by NO. NH3 and HCl have been measured at room tempera& by studying 'he emissions of singlet moleculx a\pg.en at 762 and 634 nm in D flowing discharge. The rate constant for deactivation of