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Absolute rate constants for the quenching of O2(b1Σg+) by unsaturated hydrocarbons

✍ Scribed by F. Stuhl; H. Niki

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
339 KB
Volume
5
Category
Article
ISSN
0009-2614

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✦ Synopsis

Absolute rate constants for the quenching of metastable 02@lCi) by acetylene. ethylene. propylene.

butene-1, tmns-butene-2, cis-butene-2, and tetramethylethylene were determined at 300%. The rate constants range from 4 to 10 X 10 -13cm3molecule-lsec-I, and exhibit a systematic variation with molecular str&ture of the olefins.

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