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Equilibrium constant for the reaction Xe+ + 2Ar ⇌ XeAr+ + Ar in the temperature range 150–300 k and the dissociation energy of XeAr+

✍ Scribed by J.D.C. Jones; D.G. Lister; N.D. Twiddy


Book ID
103015740
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
302 KB
Volume
70
Category
Article
ISSN
0009-2614

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✦ Synopsis


The equdiinum Xe+ + 2Ar * XeAr+ + Ar has been mvestigated m the temperature range l-50-300 K using a selected Ion flow tube apparatus From the temperature vanabon of the eqmliinum constant the standard enthalpy change for the reaL.tlon is determined to be -25 k 5 kJ mot-' and the dlssoclation energy of XeAr+ is estimated to be 24 f 5 Id mol-* (0.25 + 0 05 eV) At = 150 K the approach to equdiinum is consistent wzth a rate coefficient of (5 r 3) x 105' cm6 s-* for the


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