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Absolute rate constants for the gas-phase silicon-hydrogen insertion reactions of dimethylsilylene with silane and the methylsilanes in the temperature range 300-600 K

✍ Scribed by Baggott, J. E.; Blitz, M. A.; Frey, H. M.; Walsh, R.


Book ID
126318033
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
907 KB
Volume
112
Category
Article
ISSN
0002-7863

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Rate constants for the gas-phase reactio
✍ Ole J. Nielsen πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 392 KB

Rate constants for the reactions of OH radicals with CH,CHF, and CHCI,CF, have been determined over the temperature range 295-388 K and a total pressure of 1 atm. The OH rate data were obtained using the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy.