Pulsed laser photolysis, time-resolved laser-induced fluorescence experiments have been carried out on the reactions of CN radicals with CH,, CZHs, C2H4, C3H6, and C2H2. They have yielded rate constants for these five reactions at temperatures between 295 and 700 K. The data for the reactions with m
Rate constants for the reaction of OH radicals with CH3CN, C2H5CN AND CH2CH-CN in the temperature range 298–424 K
✍ Scribed by G.W. Harris; T.E. Kleindienst; J.N. Pitts Jr.
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 438 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Excess molar enthalpies \(H_{\mathrm{m}}^{\mathrm{E}}\) and excess molar heat capacities \(C_{\rho, \mathrm{m}}^{\mathrm{E}}\) of \(\left[x \mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{OH}+\right.\) \((1-x)\left\{\mathrm{HCON}\left(\mathrm{CH}_{3}\right)_{2}\right.\) or \(\left.\left.\mathrm{CH}_{3} \mat
Rate constants for the reaction of OH radicals vlith COS. CSz and CII~SCHJ, which are invo!ved in the glohal sulfur cycle, iI;IVC been determined over the temperature range 299-430 K uGng a flash ps hotolysis-resonance fluorcsccnu: tcchmque. For COS and CS2 upper limits at room tcmyzraturc of k(COS)
Absolute rate constants for the reaction of O(3P) atoms with CHI = CHF, CH2 = CHC1, and CH2 = CHBr have been obtained at 298 f 2°K using a modulation phase shift technique. The rate constants ( k z X lo-\* l./mole.sec) obtained are: CH2 = CHF (1.61 =t 0.20), CH2 = CHCl (2.54 + 0.26), and CHZ = CHBr