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Rate constants for the reaction of O(3P) atoms with CH2 = CHF, CH2 = CHCl, and CH2 = CHBr at 298 ± 2°K

✍ Scribed by R. Atkinson; J. N. Pitts JR.

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
298 KB
Volume
8
Category
Article
ISSN
0538-8066

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✦ Synopsis

Absolute rate constants for the reaction of O(3P) atoms with CHI = CHF, CH2 = CHC1, and CH2 = CHBr have been obtained at 298 f 2°K using a modulation phase shift technique. The rate constants ( k z X lo-* l./mole.sec) obtained are: CH2 = CHF (1.61 =t 0.20), CH2 = CHCl (2.54 + 0.26), and CHZ = CHBr (2.45 rt 0.25).

These rate constants are lower than those determined by discharge flow techniques, but that for CHz = CHF is in good agreement with relative rate measurements.

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