Enantioselective synthesis of some 6-deoxy-halodeoxy inositol derivatives
✍ Scribed by Adilson David da Silva; Aloisio Antonio A Benicio; Stéphane D Gero
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 236 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Total synthesis of
3 and 2-O-benzyl-3,6-dideoxy-3-chloro-D-myo-inositol
4 in optically pure form is described.
📜 SIMILAR VOLUMES
2-BenzyI-N-tert-butoxycarbonyl-1,5-imino-1,2,5-trideoxy-D-xylitol (4) and 5-amino-4benzyl-4,5-dideoxy-L-xylose (13) were prepared in optically pure form.
The synthesis of 6-deoxy-D-myo-inositol-l,3,4,5-tetrakisphosphates is described. The access to opticaly pure Ins(l,3,4,5)P4 analogues was carried out from deoxy myo inositol precursors derived from D-galactose. Modification of Ins(1,3,4,5)P4 analogues by lipophilie substituents has been investigated