Two deoxyfluoroinositols were synthesized from bromocyclohexadiene cis-diol obtained by microbial oxidation of bromobenzene with P. putidu (39D). The selective introduction of fluorine was accomplished by opening of the epoxide with teuabutylphosphoniumtluoride dihydrofluoride (TBPF-DF). The synthe
The synthesis of 5-deoxy-(±)-allose derivatives and 4-deoxy-(±)-ribose from myo-inositol
✍ Scribed by Hiroshi Fukami; Hen-Sik Koh; Tasuke Sakata; Minoru Nakajima
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 186 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The synthesis of 6-deoxy-D-myo-inositol-l,3,4,5-tetrakisphosphates is described. The access to opticaly pure Ins(l,3,4,5)P4 analogues was carried out from deoxy myo inositol precursors derived from D-galactose. Modification of Ins(1,3,4,5)P4 analogues by lipophilie substituents has been investigated
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Stereoselective Synthesis of 6-Deoxy and 3,6-Dideoxy-D-myo-inositol Precursors of Deoxy-myo-inositol Phosphate Analogues from D-Galactose. -The key step in the synthesis of the title compounds is the Ferrier rearrangement of pyranoside (II). Both resulting cyclohexanones (III) and (IV) can be trans
In the paper by G. Horne and B. V. L. Potter published in Chem. Eur. J. 2001, 7, 80, there is a mistake in the drawing of some regiochemistry of the structural diagrams in Schemes 1 ± 3. The correct structures are given below.