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ChemInform Abstract: Stereoselective Synthesis of 6-Deoxy and 3,6-Dideoxy-D-myo-inositol Precursors of Deoxy-myo-inositol Phosphate Analogues from D-Galactose.

✍ Scribed by D. DUBREUIL; J. CLEOPHAX; M. VIEIRA DE ALMEIDA; C. VERRE-SEBRIE; J. LIAIGRE; G. VASS; S. D. GERO

Publisher: John Wiley and Sons
Year: 2010
Weight: 41 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199813180

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✦ Synopsis

Stereoselective Synthesis of 6-Deoxy and 3,6-Dideoxy-D-myo-inositol Precursors of Deoxy-myo-inositol Phosphate Analogues from D-Galactose.

-The key step in the synthesis of the title compounds is the Ferrier rearrangement of pyranoside (II). Both resulting cyclohexanones (III) and (IV) can be transformed into 6-deoxy-myo-inositol. The 3,6-dideoxy derivatives (X) and (XII) are prepared from (III). -(DUBREUIL, D.; CLEOPHAX,

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