ChemInform Abstract: Enantioselective Synthesis of Some 6-Deoxy-halodeoxy Inositol Derivatives.
β Scribed by Adilson David da Silva; Aloisio Antonio A. Benicio; Stephane D. Gero
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Stereoselective Synthesis of 6-Deoxy and 3,6-Dideoxy-D-myo-inositol Precursors of Deoxy-myo-inositol Phosphate Analogues from D-Galactose. -The key step in the synthesis of the title compounds is the Ferrier rearrangement of pyranoside (II). Both resulting cyclohexanones (III) and (IV) can be trans