𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Enantioselective Synthesis of (S)-α-Arylpropionic Acids via Pd-Catalyzed Kinetic Resolution of Benzylic Alcohols.

✍ Scribed by Vinay V. Thakur; A. Sudalai

Publisher
John Wiley and Sons
Year
2005
Weight
25 KB
Volume
36
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Pd-Catalyzed kinetic resolution of benzy
Pd-Catalyzed kinetic resolution of benzylic alcohols: a practical synthesis of (R)-tomoxetine and (S)-fluoxetine hydrochlorides
✍ Iliyas Sayyed Ali; Arumugam Sudalai 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 73 KB

A convenient synthetic route to (R)-tomoxetine hydrochloride (90% ee) and (S)-fluoxetine hydrochloride (84% ee) is described. (S)-3-Phenyl-3-hydroxypropyl p-toluenesulphonate, the key intermediate, is obtained by the oxidative kinetic resolution of the corresponding racemic 3-phenyl-3-hydroxypropyl

ChemInform Abstract: Enantioselective Sy
ChemInform Abstract: Enantioselective Synthesis of β-Dibenzylamino Alcohols via a Dynamic Kinetic Resolution of α-Halo Acids.
✍ J. A. O'MEARA; N. GARDEE; M. JUNG; R. N. BEN; T. DURST 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Enantioselective Synthesis of β-Dibenzylamino Alcohols via a Dynamic Kinetic Resolution of α-Halo Acids. -The title compounds (IV), precursors of synthetically important Reetz aldehydes, are prepared by highly diastereoselective amination of α-bromo esters (I). The high yields obtained in this amin

Synthesis of Optically Active α-Hydroxy
Synthesis of Optically Active α-Hydroxy Acids by Kinetic Resolution Through Lipase-Catalyzed Enantioselective Acetylation
✍ Waldemar Adam; Michael Lazarus; Alexandra Schmerder; Hans-Ulrich Humpf; Chantu R 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 322 KB 👁 1 views

The lipase-catalyzed acetylation of a broad spectrum of configurations of the 2-hydroxy acids 1 were assigned by comparison of the gas-chromatographic data with that of racemic 2-hydroxy acids 1 to their 2-acetoxy acids 2 was shown to proceed with high enantioselectivity. Thus, the literature-known

Enantioselective Synthesis of Chiral β-A
Enantioselective Synthesis of Chiral β-Aryloxy Alcohols by Asymmetric Hydrogenation of α-Aryloxy Aldehydes via Dynamic Kinetic Resolution
✍ Zhang-Tao Zhou; Jian-Hua Xie; Qi-Lin Zhou 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 1 views

## Abstract magnified image A catalytic enantioselective hydrogenation of racemic α‐aryloxy aldehydes __via__ dynamic kinetic resolution has been developed by using (diamine)(spirodiphosphine)ruthenium(II) chloride [RuCl~2~(SDPs)(diamine)] catalysts. Employing this new reaction system a variety of